Pili, officially the Municipality of Pili is a 1st class municipality and capital of the province of Camarines Sur, Philippines. According to the 2020 ce…Pili, officially the Municipality of Pili is a 1st class municipality and capital of the province of Camarines Sur, Philippines. According to the 2020 census, it has a population of 99,196 people. The town is 450 kilometres from Manila.